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Detection Capabilities for ICP-MS (EPA Method 1638)

Metal
MDL ppb
LOQ ppb
ML
ppb
Recommended
Analytical m/z
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Manganese
Molybdenum
Nickel
Selenium
Silver
Thallium
Thorium
Uranium
Vanadium
Zinc
0.1
0.01
0.1
0.01
0.01
0.01
0.02
0.005
0.01
0.005
0.01
0.008
0.09
0.3
0.009
0.004
0.01
0.004
0.01
0.04
0.3
0.03
0.4
0.03
0.04
0.03
0.06
0.017
0.04
0.015
0.03
0.025
0.30
1.1
0.028
0.012
0.03
0.014
0.03
0.1
0.5
0.05
0.5
0.05
0.05
0.05
0.05
0.02
0.05
0.02
0.05
0.02
0.2
1.0
0.02
0.01
0.05
0.01
0.05
0.1
27
121
75
138
9
114
52
59
63
206, 207, 208
55
98
60
82
107
205
232
238
51
66

 

Notes

1. Method Detection Limit as determined by 40 CFR Part 136, Appendix B.

2. Minimum Level (ML) calculated by multiplying laboratory-determined MDL by 3.18 and rounding result to nearest multiple of 1, 2, 5, 10, etc. in accordance with procedures used by EAD and described in the EPA Draft National Guidance for the Permitting, Monitoring, and Enforcement of Water Quality-Based Effluent Limitations Set Below Analytical Detection/Quantitation Levels, March 22, 1994.